The Wexler Group is led by Robert B. Wexler, Assistant Professor in the Department of Chemistry at Washington University in St. Louis. We develop computational methods and use them to study materials for hydrogen production, CO2 conversion, and solar energy conversion.

Research Overview

Research Areas

Surface phase diagram with ordered, disordered, and gas-phase adsorbates

Surface Phase Diagrams

First-principles calculations and nested sampling predict catalyst surface structures as functions of temperature and pressure.

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Solar thermochemical hydrogen-production cycle for a redox-active perovskite

Solar Thermochemical Hydrogen Production

We design redox-active perovskites for solar thermochemical water splitting.

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Halide-dependent synthesis pathways to wurtzite and rock-salt manganese sulfide nanocrystals

Nanocrystal Synthesis

We study how precursors affect the crystal structure and phase of chalcogenide nanocrystals during synthesis.

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Selected Publications

Surface Phase Diagrams from Nested Sampling

Phys. Chem. Chem. Phys. · 2024

First-principles calculations and nested sampling predict catalyst surface structures as functions of temperature and gas pressure.

Large-Scale Experimental Validation of Thermochemical Water-Splitting Oxides Discovered by Defect Graph Neural Networks

Mater. Horiz. · 2026

Defect graph neural networks identified candidate thermochemical water-splitting oxides for experimental validation.

Equilibrium Thermochemistry and Crystallographic Morphology of Manganese Sulfide Nanocrystals

arXiv · 2026

Equilibrium thermochemistry predicts the crystal phase and morphology of manganese sulfide nanocrystals.

Principal Investigator

Robert B. Wexler

Robert B. Wexler

Assistant Professor of Chemistry, Washington University in St. Louis

Wexler develops and applies first-principles calculations, Monte Carlo simulations, and machine-learning methods to model interfaces relevant to catalysis, solar energy conversion, and nanocrystal synthesis. He was a postdoctoral researcher at Princeton University from 2019 to 2022 and received his Ph.D. from the University of Pennsylvania in 2019.

Recruitment

The Wexler Group is recruiting Ph.D. students for all ongoing research projects. Prospective graduate students apply through the Washington University Department of Chemistry. WashU undergraduates and prospective postdoctoral researchers may inquire by email.

Methods and Software Research Papers